Fatigue and Corrosion in Metals

The author dedicates a particular attention to corrosion starting with an electrochemical treatment that mechanical engineers with a rather limited knowledge of electrochemistry will well digest without any pain. The electrochemical introduction is considered an essential requirement to the full understanding of corrosion that is essentially an electrochemical process. All stress corrosion aspects are treated, from the generalized film rupture-anodic dissolution process that is the base of any corrosion mechanism to the aggression occurring in either mechanically or thermally sensitized alloys up to the universe of hydrogen embrittlement, which is described in all its possible modes of appearance. Multiaxial fatigue and out-of-phase loading conditions are treated in a rather comprehensive manner together with damage progression and accumulation that are not linear processes.^

Load spectra are analyzed also in the frequency domain using the Fourier transform in a rather elegant fashion full of applications that are generally not considered at all in fatigue textbooks, yet they deserve a special place and attention. The issue of fatigue cannot be treated without a probabilistic approach unless the designer accepts the shame of one-out-of-two pieces failure. The reader is fully introduced to the most promising and advanced analytical tools that do not require a normal or lognormal distribution of the experimental data, which is the most common case in fatigue. But the probabilistic approach is also used to introduce the fundamental issue of process volume that is the base of any engineering application of fatigue, from the probability of failure to the notch effect, from the metallurgical variability and size effect to the load type effect.^

Fractography plays a fundamental role in the post mortem analysis of fatigue and corrosion failures since it can unveil the mystery encrypted in any failure.